Contain all the articles from this issueNitrous oxide decomposition over Fe-ZSM-5 catalysts prepared by different methodsMircea Teodor Nechita, Ioan Rosca, Daniel Sutiman, Gabriela Apostolescu, Ioan Iordache Geometrical correlation method for global estimation of the ecosystem stateCamelia Popa, Cornel Cojocaru, Matei MacoveanuImmobilized lipases as biocatalysts for organic synthesis 1. Transesterification of ethyl acetate with alcohols in the presence of free Candida antarctica lipase BBrindusa...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25181

AbstractThe purpose of this study was to investigate the immobilization of denitrifying bacteria on microbial cellulose (MC) for biological denitrification. A novel denitrifying bacterium, Pseudomonas stutzeri, was immobilized in microbial cellulose and introduced into an up flow packed bed reactor in order to remove nitrate from synthetic influent. The MC presented the high biomass concentration throughout the experiment, achieving 3.4 mg biomass/g support. The efficiency of the system for deni...
Autori: Abbas Rezaee, Hatam Godini, Hossein Bakhtou
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25302

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractThis study deals with the radiolytical decomposition of water molecules, in the presence of some catalysts, getting out hydrogen as unpolluting and cheaper energy vector. Instead of the spent nuclear fuel elements taken out from nuclear power plants, as irradiation source it was used the 60Co radionuclide having a specific activity of 1.1.105 Ci. It was observed that the radiolytic yield of resulted molecular hydrogen from water radiolysis in the presence of used catalysts decreased as:N...
Autori: Ada Macovei, Alexandru Cecal, Dumitru Ganju, , Oana R. Haută
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25354

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

AbstractThe purpose of this study is to analyze the recycling potential of printing papers, which are obtained by two different filler loading processes: conventional loading by direct addition of calcium carbonate to cellulose fiber suspension and in-situ loading by precipitating calcium carbonate within cell wall and lumen of pulp fibres. In order to evidence the influences of the both filler content and loading method, a reference sample for recycling was obtained without filler, but using th...
Autori: Maria Ciobanu, Elena Bobu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25386

Abstract A new type of wire-cylinder plasma reactor, in which air flow shapes into gas torches is developed. The decomposition performance of toluene in contaminated air flow induced by pulsed corona discharge in the reactor is investigated experimentally under atmosphere pressure and room temperature. It is found that the decomposition efficiency is affected dramatically by air introduction way, and the ejection stimulates the decomposition of toluene compared with the conventional method. T...
Autori: Zhihui Xie, Lingen Chen, Fengrui Sun, Qizheng Ye
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25402

Abstract Textile industry is one of the most pollutant and water consuming industries. Large quantities of water are required in materials preparation and dyeing, so consumption and waste generation have become serious concerns for textile manufacturers and finishers. Textile effluents are characterized by high values of quality indicators such as BOD and COD, suspended solids and heavy metals. A serious environmental problem and also an aesthetic problem is the color of the effluent. Reactiv...
Autori: Daniela Cailean, George Barjoveanu, Corina - Petronela Musteret, Liliana Rozemarie Manea, Nicolae Sulitanu,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25420

Abstract Changing fuel consumption to a more ecological environmentally alternative is replacing fossil fuels with fuels generated from renewable resources. Ethanol, a renewable fuel, can be produced mainly from crops, lignocellulosic biomass and different other environmental wastes. Although ethanol has been produced mainly from crops, there is a great interest in using cheaper lignocellulosic materials as a feedstock for ethanol production. The aim of this paper is study of dilute acid hyd...
Autori: Ionel Balcu, Adina-Elena Segneanu, Marius Constantin Mirica, Mirela Ioana Iorga, Corina Macarie, Raluca Martagiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25481

Abstract The textile wastewaters have a diverse composition depending both on the used raw materials and applied manufacturing technologies. These wastewaters may contain various pollutants such as organic compounds (e.g. residual dyes), suspended solids, metal ions etc. Most of dyes are synthetic compounds with aromatic molecular structures and non-biodegradable. The oxidative destruction via homogenous oxidation processes with hydrogen peroxide (simple chemical oxidation with H2O2 or advanc...
Autori: Carmen Zaharia, Daniela Suteu, Augustin Muresan, Rodica Muresan, Alina Popescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25570

? MUNICIPAL SOLID WASTE LANDFILLING AND TREATMENT OF RESULTING LIQUID EFFLUENTS ? ROMANIA: ENTREPRENEURIAL VALUES AND SUSTAINABILITY ? THE COMPRESSIVE STRENGTH OF WOODEN BRIQUETTES USED AS RENEWABLE FUEL ? ECO-FRIENDLY EXTRACTION AND SEPARATION METHODS OF CAPSAICINES ? ADDRESSING ISSUES OF GEOENVIRONMENTAL RISKS IN DOBRUJA, ROMANIA/BULGARIA ? ADSORPTION OF 2,4-DINITROPHENOL AND 2,6-DINITROPHENOL ONTO ORGANOCLAYS AND INORGANIC-ORGANIC PILLARED CLAYS ? APPLICATION O...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25659

Abstract:In this paper, the influence of two types of imidazolium-based ionic liquids (ILs) on the properties of sycamore maple (Acer pseudoplatanus) veneers, at 25 0C, 60 0C and 80 0C has been studied by using contact angle measurements and Fourier transform infrared spectroscopy analysis. The measurements showed that wood wettabillity is increased by IL treatment. It has been determined that the ILs decrease the crystallinity and improve the flexibility of the cellulose matrix. Also, it has be...
Autori: Attila Porzsolt, Catalin Croitoru, Christian Friedrich, Silvia Patachia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25737

Abstract:Our research was focused on developing some new procedures to reduce the biodegradable wastes by composting. The aim of thisstudy was to obtain and asses at laboratory scale the maturity of three compost samples of different proportion of vegetable waste,beech sawdust and sewage sludge by analyzing their FT-IR spectra and C/N ratio. The composting process was monitored by testsperformed weekly on the three samples in order to investigate the physical parameters (pH and electroconductivi...
Autori: Anca Sauciuc, Claudia Zaha, Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25772

The corrosion products of high strength low-alloyed steel and of cast iron, maintained a prolonged period in natural seawater, were analyzed. A part of the corrosion products are soluble compounds of divalent and trivalent iron, the iron dissolution being accelerated when divalent ions are formed and in the case of the aerated seawater. The solid corrosion product formed during corrosion in seawater is principally oxy-hydroxide (FeOOH), but were identified small quantities of Fe2O3, Fe3O4 and so...
Autori: Daniel Mareci, Maria Lungu, Nicanor Cimpoeşu, Nicolae Aelenei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25832

Biomass is a very interesting natural source to obtain renewable energy as well as chemical products based on a renewable feedstock. Fuel produced from renewable resources is widely regarded as an option to substitute traditional fossil fuels and thus to answer to the adjunct climate debate. For the production of chemical substances from renewable substrates many process options are in investigation worldwide at the moment. However the ecological benefits of these technological options have to b...
Autori: Anton Friedl
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25856

The aquatic species are permanently subjected to various stresses through the ecosystem and the food habit. Elucidating the impact at the cellular level allows us to understand the ways in which the polluting elements and their derivatives can disrupt the metabolism of aquatic organisms triggering apoptosis in individual cells or necrosis affecting groups of neighbouring cells. The aim of this preliminary study is to highlight the influence of the environmental factors on two fish population by ...
Autori: , Camelia Ureche, Dorel Ureche, Gabriel Lazar, Ileana Denisa Nistor, Irina Loredana Ifrim, Iuliana Mihaela Lazar, Marius Stamate, Valentin Nedeff
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25861

AbstractPolyvinyl alcohol (PVA) is a typical refractory organic pollutant with low biodegradability and high molecular weight. Thispaper presents data on the radiolysis of PVA in aqueous solutions by using ionizing radiation. Response surface methodologywith Box-Benhken design of experiment was applied to analyze the interactions among initial concentration of PVA, absorbeddose, and initial pH of aqueous solutions on PVA removal efficiency. 9.4-89.4% PVA was removed based on differentcombination...
Autori: Jianlong Wang, Jinping Tian, Lujun Chen, Shijun He, Weihua Sun
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25967

AbstractThe transport of gases and solvents in polymeric membranes is an important phenomenon with many technical applications, suchas the mixture separation using polymeric membranes, the polymeric membrane preparation, the polymer devolatilization and theselection of appropriate polymeric membranes for a certain process. In most membrane separation operations and manufacturing,equilibrium and diffusion data are required.Useful information on equilibrium and diffusion can be obtained from the s...
Autori: Ciprian Constantin Negoescu, Eugenia Teodora Iacob Tudose, Ioan Mămăligă, Nicoleta Bunduc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25975

AbstractIn the last years many papers have reported about the occurrence of the pharmaceuticals in the surface waters and theirundesirable effects upon the aquatic life. Most of pharmaceuticals pass through the wastewater treatment plants unchangedbecause they are biorefractory compounds and as a result they enter the water bodies. Therefore, it is necessary to improve thebiodegradability of pharmaceuticals effluents (PhEs) before their discharge in the sewerage systems. The aim of this paper wa...
Autori: Carmen Lazău, Florica Manea, Monica Ihos
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26021

AbstractThe paper describes the synthesis of nanocrystalline zinc ferrite starting from 1,4-butanediol and a mixture of zinc and ironnitrates. During the heating of the obtained solution, a redox reaction takes place with emission of brown nitrogen oxides andformation of a solid powder. This powder was characterized by thermal analysis and FT-IR spectrometry, techniques thatconfirmed the formation of a mixture of zinc and iron carboxylates. This mixture was further used as precursor for zinc fer...
Autori: Cornelia Muntean, Marcela Stoia, Paul Barvinschi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26029

Mother Earth Investments AG, is actively working onthe development 2nd generation bioenergy feedstocks.In this book, Mr. Jansen generously shares hisknowledge in the field, in particular, regarding thechallenges and opportunities in development ofbiomass-derived fuels. This essential guide toinvesting in bioenergy commodities details secondgeneration biofuels from a scientific, technical andeconomic perspective, and discusses their globalenvironmental, political and financial impact.The book is ...
Autori: Roland A. Jansen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26100

The book edited by Haibo Xie and NicholasGathergood focuses on one of the most importantscientific issues of the 21 century which is thereplacing fossil fuel with sustainable alternatives suchas biomass. Fossil fuels are conventional rawmaterials for many industrial sectors includingchemical and energy production. Usage of fossil fuelis limited by their availability, price and carbonfootprint. Biomass is a renewable resource globallyavailable, cheaper and carbon sequestering. Step bystep shiftin...
Autori: Adrian Catalin Puitel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26101

AbstractThermal behaviour, microstructure and mechanical properties of the clay polluted by acidic and alkaline pollutants wereinvestigated by thermogravimetric/differential thermal analysis (TG-DTA), scanning electronic microscope (SEM), mercuryintrusion experiments, permeability coefficient and unconfined compressive strength tests. The clay polluted by alkaline solutionpresented distinct exothermic peaks at 304-310oC, while it’s not observed for the one polluted by acidic solution due to thed...
Autori: Zhao Ying
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26182

AbstractIn this study, changes induced in milk processed at ultra high temperature (UHT) were investigated following exposure to UVand white-light, by employing fluorescence spectroscopy. Two important indicators, namely Riboflavin (Rb) and vitamin A,were monitored to evaluate the light-induced damage in milk. It was noticed that the photo-degradation of Rb is due to thephotochemical decomposition and photosensitization. Moreover, it was found that the wavelength of the exposure light has agreat...
Autori: Maria Iliut
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26241

AbstractThis paper continues the previous investigations regarding the technology for the Aluminum (Al) recovery as Al sulfate fromblack Al slag. Leaching is the next compulsory step in the Al extraction process. The paper studies the influence of mothersolutions´ (MS) recirculation resulted from the process within the system over the quality of Al sulfate and the siliceous residue(R) and, the aluminum nitride (AlN) hydrolyses in the leaching process. The optimum parameters determined are: *the ...
Autori: Romanita Teodorescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26250

AbstractInvestigations on thermochemical transformation of asbestos fibers followed by computer aided image analysis are presented.Asbestos Containing Wastes (ACW), notably asbestos-cement, were characterized before and after microwave heating withadditives aimed at reacting with and transforming asbestos fibers. Microprobe analysis helped determine the chemicalcompositions. X ray diffraction (XRD) was used to confirm decomposition of asbestos fibers during microwave heating. Electronparamagneti...
Autori: Yan Yvon
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26256

AbstractAnaerobic degradation (AD) of municipal solid waste (MSW) depends on the moisture and nutrient distribution within thebioreactor; these factors are affected by leachate recirculation. In this work, the effects of leachate recirculation of 15 to 120 byvolume percentage (%V) on AD were studied. The ojectives of this study are as follows: a) to determine which recirculation rateprovides the best conditions for accelerated anaerobic degradation (AD) and b) to determine the optimal range of r...
Autori: Maria del Consuelo Hernández-Berriel
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26557

Abstract The utilization of manure for waste-to-bioenergy conversion processes may be a sustainable development choice rather than its traditional use as a fertilizer. Furthermore, the valorization of manure via thermochemical conversion routes and their integration with biological processes can provide an additional pathway in the utilization of residual biomass. On the other hand, the use of metal oxides might enhance the performance of thermochemical processes such as pyrolysis by either ...
Autori: Maria Fernandez-Lopez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26647

Abstract Hydrogel membranes obtained by neat polyvinyl alcohol (PVA) or PVA with various bio insertions like: Scleroglucan (Scl), Zein (Zein) or Cellulose (Cel), were subjected to diffusion and sorption/desorption experiments using different type of dyes such as: Crystal Violet (CV), Methylene Blue (MB), Congo Red (CR). If the sorption, desorption or diffusion of a dye in/from/through a hydrogel is usually monitored by the dye solution analysis, in this case the transport phenomena are follo...
Autori: Adina Papancea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26649

Abstract In the current study, the structural and adsorptive properties of the micro crystalline cellulose beads, Cellets 200 and 350, as well as the possibility to use them as adsorbents for removal of reactive dye Brilliant Red HE-3B and cationic dye Methylene Blue from aqueous solutions have been investigated. Batch experiments were conducted to study the effect of adsorbent particles size (200-500 μm), initial solution pH (1-11), adsorbent dose, dye concentration, temperature (2-450C)...
Autori: Daniela Suteu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26668

Abstract The deterioration of the natural polymers is a very complex process, and a problem that can be best addressed through modelling. The approach for modelling the rheological behaviour of different cellulose-based textile fibres (cotton, hemp, flax) when subjected to a hydrothermal treatment, followed by exposure to different doses of gamma-rays (5, 10, 15 and 25 kGy) is presented here. In order to predict the optimum radiation dose limit and hydrothermal aging time, the mathematical m...
Autori: Angelica Olaru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26678

Abstract MFe2O4 nanopowders (M = Ni, Co, Cu) were prepared using the precursor technique, starting from the corresponding metal nitrates and poly(vinyl alcohol)-PVA. During the heating of metal nitrates- PVA solution, a redox reaction takes place around 150°C, leading to the formation of M(II) and Fe(III) carboxylates. These compounds were used as precursors for the ferrites nanopowders. The desired ferrites were obtained by thermal decomposition of the carboxylates; the obtained...
Autori: Marcela Stoia
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26745

Abstract Solid digestate (SD) represents an environmental problem due to the continuous increase of biogas production. In the present study four white-rot fungal strains were screened for their ability to grow on two different SD samples, obtained from industrial biogas plants, using wheat straw (WS) as a control medium. Results show that i) the feedstock used in the biogas plant influences the time required for the colonization of the corresponding SD and ii) different fungal strains have d...
Autori: Guglielmo Santi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26792

Abstract For the purpose of evaluating the effect of environmental regulations addressing Energy Conservation and Emission Reduction (ECER) on Chinese industry, this paper introduces a non-radial, non-oriented and slacks-based data envelopment analysis (DEA) model, energy conservation and undesirable output reduction slacks-based Malmquist index (EUSM index) and its decompositions. This model can simultaneously measure energy and non-energy inputs along with pollutant emissions in addition t...
Autori: Jing Xiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26805

Abstract In the present study, several selected formulations based on recycled (rPP) or virgin polyolefins (vPP) and lignocelluloses were prepared and subjected to microorganism attack. Biodegradation tests were performed with microbial strains belonging to fungal genera, like Aspergillus, Penicillium and Fusarium. The initiation of biodegradation was demonstrated by Scanning Electron Microscope (SEM) micrographs showing the colonization of surface samples by microbial strains. The crystalli...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26879

Abstract The goal of this paper is to investigate the decomposition of aqueous solutions of Azorubin (E122), i.e., an azo dye used in food industry, in a pulsed gliding arc discharge reactor (direct treatment). Air and Argon as carrier gases with solution spray has been considered, as a first approach. The bleaching of the aqueous solution was observed immediately after direct plasma treatment and the decreasing of the dye concentration have been emphasized. Further more, the dye concentrati...
Autori: Marius Ursache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26898

One way to improve the performance of non-thermal plasma (NTP) reactor for volatile organic compound decomposition is by the introduction of ferroelectric materials into the discharge zone of NTP. This paper is a review of the breakthroughs and the current status of the applications of this technology for the abatement of volatile organic compounds (VOCs). It covers the process of energy generation in NTP, VOCs decomposition processes and the effects of critical factors such as type of packed...
Autori: Abdullahi Mohammed Evuti
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26948

Biomass is a very important source for the production of biofuels. During the hydrolysis step of the process for obtaining biofuels the rate of decomposition of biomass is strictly related to its organic matter content and the operating mode of the facilities. This paper highlights the effect of different pretreatments on the composition of biomass at the molecular level using Fourier Transform Infrared Spectroscopy (FTIR) and Principal Component Analysis (PCA). For this experiment, a mixture...
Autori: Andreea Cocarcea Rusei
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26986

The Lake Bacau I, located in Bacau City, Romania was built in 1966 with a double purpose: as reservoir belonging to the energy system of the Bistrita River and to provide the water needed for the industrial units located in the area. Also, for more than 40 years, the lake was used by the same plants to discharge the wastewater, more or less treated. In present, most of the industrial units are closed and the discharge of wastewater in the lake is banned, the area being used mainly for recreat...
Autori: Maria-Ema Faciu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26987

High contents of colloidal and organic materials in municipal wastewater sludge cause problems in the process of dewatering. The filtering efficiency can be improved by chemical conditioning, but the effectiveness of mechanical dewatering is limited because flocculated sludge is highly compressible. Physical conditioners such as bagasse can be used to facilitate mechanical dewatering. This paper describes the use of bagasse pith (cane sugar waste fiber) to improve the dewatering process of mu...
Autori: Nematallah Jaafarzadeh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26995

In this study, it was aimed to determine the relationship between the temperature decrease of the air passing through the pad and flow rate of pad wetting water for pad evaporative cooling. In the experiments, a commercially available cellulose based evaporative cooling pad (CELdek®7060-15 pad) was used. Experiments were conducted at three different water flow rates (2 L min-1 m-2; 4 L min-1 m-2 and 6 L min-1 m-2) and two different air velocities (1.0 m sec-1 and 1.5 m sec-1). The tempera...
Autori: Cengiz Karaca
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27006

In this paper both kinetic and thermodynamic parameters of thermochemical transformation of waste tires are evaluated by using thermogravimetric analysis (TGA). For rubber thermochemical decomposition, individually and in the presence of other tires components, some kinetic and thermodynamic parameters such as energy of activation (Ea), frequency factor (A), reaction enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) have been calculated by using the integration method. The e...
Autori: Sana Kordoghli
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27060

This study highlights the potential use of yellow Zea mays seed chaff (YZMSC) biomass as a biosorbent for the removal of Cr3+, Cd2+ and Pb2+ ions from aqueous solutions. Fourier transformed Infrared analysis of the biomass suggests that YZMSC biomass is basically composed of cellulose and methyl cellulose. The biosorption capacities, qmax, of YZMSC biomass for Cr3+, Cd2+ and Pb2+ are 14.68, 121.95 and 384.62 mg/g respectively. Biosorption equilibrium was achieved at 20, 30 and 60 min for Cr3+...
Autori: Jonathan Oyebamiji Babalola
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27083

The roots of this study are generated by the problems of plastic waste accumulations: insufficiency of storage spaces, storage costs and outgoings of plastic waste recycling, recovery, decomposition or reprocessing. The paper develops and details a modular prototype, for multifunctional territorial use, offering non-polluting and aesthetic possibility of plastic waste storage. The progress in the related fighting pollution areas have been approached, such as waste management through ecologica...
Autori: Doina Mira Dascălu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27112

Carbadox is a veterinary antibiotic and widely used in livestock production as feed additives. Carbadox and its metabolites have the potential of provoking a tumor-inducing mutation. In this study, the influence of carbadox addition on composting performance and its removal during thermophilic composting were investigated. The results showed that the carbadox addition slightly influenced pH variation and C/N ratio, and also improved the decomposition of organic matter. However, XRD analysis indi...
Autori: Lin Shi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27147

Antibiotic pollution has become one of the most important emerging soil contamination types, and has received great attentions in recent years. Understanding the microbial functional processes of soil ecosystems under antibiotic contamination is of critical importance for ecological risk assessment and pollution control. In this study, the responses of soil microbial respiratory activity and ammonification were studied under different concentrations of tetracycline, chlortetracycline, and nor...
Autori: Liangyin Yi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27151

The effectiveness of thermal insulation materials mostly depends on their thermal conductivity. The low thermal conductivity is predetermined by density, structure, moisture content and temperature of material and, considerably less, by other indices. Loosefill cellulose insulation is allocated to the group of materials, the density of which fluctuates within large limits. This property is related not only to application of cellulose wool in different constructions, but also to technological ...
Autori: Sigitas Vėjelis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27165

Hesperaloe funifera was studied as a new raw material for paper manufacturing and lignin recovery. An experimental design was carried out to improve the quality of the obtained pulp varying the process temperature (155, 170 and 185 ºC), time reaction (20, 40 and 60 minutes) and soda concentration (5, 10 and 15 %). All experiments were carried out with 1% anthraquinone. Lignin content, holocellulose content, α-cellulose, viscosity, Kappa number and drainability were determined in the d...
Autori: MŞ Ángeles de Andrés
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27185

Catalysts based on nanocrystalline Mg-Zn ferrites supported on commercial alumina were prepared by in situ sol-gel auto-combustion technique. The as-obtained materials were characterized using Fourier Transform Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), atomic force microscopy (AFM) and Brunauer-Emmett-Teller (BET) specific surface area measurement. These materials were tested as catalysts for hydrogen peroxide decomposition and phenol oxidation reactions. The catalytic activity of ...
Autori: Tamara Slatineanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27192

This study aims to evaluate the effects of Fe2+ present in carbonated natural mineral waters on the decomposition of hydrogen peroxide (H2O2) used as sanitizing agent of the collector water tanks and the oxidation of NH4+ to NO3– and NO2– nitrogen compounds from bottled carbonated natural mineral water by the Fenton process. This evaluation suggests that the distribution of the nitrogen compounds, at certain concentrations of H2O2 is influenced by facilitated Fenton reaction in the p...
Autori: Daniela Bogdan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27279

The remarkable photocatalytic properties of titanium dioxide and the high adsorption capacity of the mesoporous materials were combined to obtain active photocatalysts for the decomposition of Rhodamine 6G dye. The mesoporous TiO2 was obtained by the controlled hydrolysis-condensation of titanium isopropoxide, using hexadecyl-trimethyl-ammonium bromide as template, followed by calcination to remove the organic matter. Subsequently, this sample was doped with sodium wolframate and platinum. T...
Autori: Doina Lutic
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27325

Inventory and monitoring of total organic carbon stock (TOC) it’s an issue of actuality in the context of breaking into the atmosphere an alarming quantity of CO2 result of human activities. Management and sustainable management of forest and agricultural ecosystems can have a positive influence on maintaining optimal stock of carbon sequestered. A case study achieved in the Humor catchment reveals that changing the land’s utility means important modifications in the quantity of the ...
Autori: Eugen Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27336

Lignocellulosic residues are relatively recalcitrant to bioconversion during anaerobic digestion (AD) for biogas production. Pre-treatments with cellulolytic enzymes or diluted alkali can facilitate biomass hydrolysis and enhance the process. Both pre-treatments require low energy and chemical inputs, without accumulation of inhibitor. Milled wheat straw was pre-treated with hydrolytic enzymes or with diluted NaOH before AD. The pre-treatments were performed on sterilized, stabilized with formic...
Autori: Ciro Vasmara
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27420

Turfy soil is a special soil formed in the swamp environment with the incomplete decomposition of plant residue. On one hand, the special engineering geological properties of turfy soil such as high compressibility, high moisture content, high void ratio, will cause great difficulty with engineering construction in turfy soil area, this study will make it clear of parameters value for engineering design. Turfy soil, on the other hand, is a part of the wetland, the essence of protection of the...
Autori: Lei Nie
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27445

A total of 152 different actinomycetes isolates were recovered from samples that were collected from different ecosystems of Algeria. The desert soil of Bousaada gives the greatest number of actinomycetes compared to others soils. The first screening indicates that 63.15 % of the isolates were able to produce carboxymethyl cellulase enzyme. Isolates were evaluated for their cellulase activity by growing in carboxymethyl cellulose broth. B-PNG23 isolate is one of the isolates displayed a high enz...
Autori: Azzeddine Bettache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27451

The purpose of this paper is to present the results regarding the obtaining of reducing sugars at the enzymatic hydrolysis of the lignocellulosic material, wheat straws. For these, the lignocellulosic material was submitted to a preliminary pretreatment for destruction of the cellulose crystalline structure and to increase the material's susceptibility to the enzymatic attack. The preliminary pretreated material with diluted acid (0.5%-4%) or with water at different temperatures (120-170&ord...
Autori: Eufrozina Albu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27463

This study undertakes to characterize through thermal analysis in dynamic conditions a wide range of building materials used for various types of insulation and presents for the first time a comparative analysis of their thermal stability. To this effect, the dynamic thermal analysis TG/DTG was applied. The results show a degradation resulting in one, two or three stages after a complex mechanism, with different mass loss, depending on the structure and atmosphere in which the thermal decomposit...
Autori: Andreea-Camelia Sprânceană
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27514

The aim of the studies was to evaluate the influence of the 30-year operation of a small retention reservoir fed with water from a forest-agricultural catchment area on the contents of selected mineral elements substances in bottom deposits. The studies were carried out in the Łoje dam reservoir (N 53o7’28’’, E 20o48’20’’), supplied by the regulated Łojówka stream. Deposit samples were collected in four transects perpendicular to the reservoir...
Autori: Ireneusz Cymes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27518

This paper introduces basic information on the biodegradation of polymers as well as the mechanisms of degradation and factors influencing this process. This paper describes prodegradant additives that induce decomposition of polymers to biodegradable compounds with regard to additives causing oxo-biodegradation. Based on the results of experiments conducted for molded pieces made of polypropylene and extrudates made of low density polyethylene with a d2w prodegradant additive, dependences betwe...
Autori: Tomasz Jachowicz
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27519

The synthesis and the study of the complexes obtained in this paper represent the beginning of our research for applied coordinative compounds of this type in agriculture. The analysis and the study of Mn(II) complexes with DL-β-Aminoisobutyric acid as ligand were accomplished in aqueous and alcoholic solution and also in solid state.The composition ratios and the stability of the synthesised compounds were analysed with specific methods: conductance, pH measurements, spectrophotometry and ...
Autori: Doina Sibiescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27549

Two multiple linear regression (MLR) models were developed with the aim to estimate the decomposition temperature of a series of polyimides. Two parameters, Tni and Tai, corresponding to the temperature of 10 % weight loss of the sample, determined by dynamic thermogravimetric analysis under conditions of N2 inert atmosphere and air, respectively, were used as a criterion for thermal stability. The obtained MLR models correlate thermostability with a series of characteristics of the studied poly...
Autori: Catalin Lisa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27556

A simple and efficient method for preparing Ag-doped TiO2 nanoparticles was successfully developed, by associating the sol-gel method and the impregnation-reduction. While titanium dioxide is one of the most used solids as photocatalyst, silver is particularly interesting for applications in biological and chemical detection and for its antibacterial properties. Moreover, in photocatalysis silver acts as an electron sink and donor in capturing the photogenerated electrons. The structural and mor...
Autori: Catalina Nutescu Duduman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27566

β-glucosidases are very important in the improvement of cellulose degradation rates by diminishing the inhibition of end products. Although, cellulase cost has reduced significantly in last decade but still the high costs of biomass saccharification is one of the main challenges for the commercialization of ethanol from LC biomass. In this work, β-glucosidase immobilization in calcium alginate was optimized using response surface methodology. 89% immobilization efficiency was achieved ...
Autori: Ruchi Agrawal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27614

Within this study a total content of 20 elements was determined in 25 soil samples taken from the vicinity of the "Buchim" mine, Republic of Macedonia, covering an area of 14.2 km2. The results have been compared to new Dutchlist and NOAA standards and it was concluded that the content of As, Cd, Cu, Pb and Zn in most of the samples is over the corresponding optimal or action values probably due to the anthropogenic activities. Thus As values ranged 13.1-225 mg kg-1 with 20 above the o...
Autori: Todor Serafimovski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27844

A study on the biodegradability of several formulations based on poly[vinyl alcohol] (PVA) and wood flour has been carried out. Basically, all formulations are based on PVA and wood flour, and the influence of starch, glycerol and/or polyvinyl chloride (PVC) incorporated in some of them was investigated. Biodegradation was performed by incubation of the composites with a selected Aspergillus niger strain able to act as an polymer biodegrading agent. The composites biodegradation was evaluated...
Autori: Luiza Jecu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27886

The influence of initial metal ion concentration and temperature on the adsorption of Zn(II) from aqueous solution onto amino ethyl cellulose (AEC) functionalized with Orange 16 reactive dye, was examined. Batch experiments were performed at pH of 4.0 and adsorbent dose of 8.0 g/L previously established as optimum, ranging the initial Zn(II) concentration between 22.74-181.92 mg/L and temperature between 2 and 60 C. Three isotherm models (Langmuir, Freundlich and Dubinin – Radus...
Autori: Gabriela Nacu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27904

Considering world energy demand and its security, much attention has been focused on identifying promising lignocellulosic substrates to generate a variety of downstream fuels and chemicals. In response, a recent key research area has centered on hydrolysis of cell wall polysaccharides by various physical, chemical and biological means. Due to their complex chemical and molecular structure, there is a substantial knowledge gap in understanding of biomass recalcitrance and its relationship wit...
Autori: Nadeem Akhtar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27908

Being able to estimate the quantity of pollutants that can be spread in the environment is a factor of paramount importance in the industrial panorama. In order to accomplish such aim, a crucial step is the estimation of the so-called source term, that is the rate of generation (or release) of a substance in a generic process. A proper estimation requires to consider both the machinery and the unit operations present into the analysed system. For such reasons, ad hoc considerations and models...
Autori: Marco Barozzi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27964

The main objective of the research was to study the efficiency of the glyphosate amine pesticide mineralization in wastewaters (real and model type of wastewaters respectively) using ozonation treatment as an advanced oxidation processes (AOP). The wastewater samples (model wastewater) were obtained by mixing a given volume of the stock solution prepared from glyphosate isopropyl-amine in different volumetric ratios with distillated water and with real wastewater obtained from a domestic wastewa...
Autori: József Németh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28050

The Cellets product represents a cellulose material, which combines different properties such as the perfect sphericity, fine particle size distribution, low friability and solubility, and inertness. The experiments were carried out with Cellets 200 granulated celluloses used as a filling material for a laboratory glass column, using diluted dye solution (9-10 mg of dye /L of solution) at adequate initial pH (4.7). The effect of flow rate was investigated, and the modeling of experimental data f...
Autori: Iulia Nica
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28155

This present study, investigates the performance of activated sardine scale powder (ASSP)/ Cellulose acetate (CA)/Polyvinylpyrrolidone (PVP) and powdered activated carbon (PAC)/ Cellulose acetate (CA) / Polyvinylpyrrolidone (PVP) composites membranes prepared by phase inversion for the elimination of humic substances (HS) from aqueous solutions. The materials and composites membranes were characterized by FTIR, XRD, SEM analyses. Overall, the results exhibit the higher performance of ASSP /CA/ P...
Autori: Naziha Sid-Sahtout
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28199

Techniques such as composting, a controlled process of decomposition of organic materials, have become fundamental to minimize the problems associated with the organic fraction of urban solid waste, as the potential to cause damage to public health, the environment and, consequently, to economic and administrative aspects can be related to this kind of waste. Microbial activity is also highlighted as a relevant factor since the microorganisms are fundamental in the degradation of organic matter...
Autori: Priscila da Costa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28222

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

Nutrients have been considered the main factor affecting microorganisms responsible for methane gas production during anaerobic digestion processes. In this study, the nutritional composition of some fruit wastes; mango (M), watermelon (W), pawpaw (P), their effects on methane gas production, and resulting energy values were assessed. Substrate samples for anaerobic digestion where prepared into various slurry treatments; M, W, P, WM, PW, MP, MWP and CONTROL. Proximate compositions of the subst...
Autori: Ogemdi Chinwendu Anika
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28233

The quality of drinking water can be kept under control through the protection of raw water sources and the permanent monitoring and control of the processes of treatment and distribution of drinking water. The dangers and risks faced by drinking water supply systems may arise from inside or outside the system. Water disinfection is the key element behind obtaining and maintaining quality. Chlorine is the most widely used disinfectant, due to its high efficiency. However, it has a major disadvan...
Autori: Alice Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28254

As one of China’s fastest growing regions, Beijing–Tianjin–Hebei (B-T-H), which contains one of the most intensive logistics networks in China, developed rapidly from 2005 to 2016. However, such growth also led to increases in energy consumption and carbon emissions. From 2005 to 2011, the growth rate of logistics carbon emissions in the B-T-H was maintained at 8%–10%. Subsequently, owing to policies and technological progress related to energy saving and emission reducti...
Autori: Jianfeng Zhao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28274

The steady increase in separate waste collection has highlighted the urgent need to adequately deal not only with urban waste (differentiated and undifferentiated) but also with special waste produced by separate waste collection and recycling processes. Source collected municipal solid waste produces different waste streams. One of this is the organic fraction of municipal solid waste (OFMSW). This fraction is central for circular economy, since it can be further transformed in order to recove...
Autori: Ivana Moscato
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28302

Healthcare wastes are produced from all medical and therapeutic activities in hospitals and healthcare centres. Around 15-20% of these wastes are classified as infectious wastes that could be hazardous. Therefore, an effective approach is required for handling costs and environmental issues. In this paper, a bi-objective Mixed-Integer Linear Programming (MILP) model is presented for logistics of infectious and non-infectious wastes. The proposed bi-objective model aims to minimize network costs ...
Autori: Mohammad Nikzamir
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28314